Phosphorescence doping in a flexible ultramicroporous framework for high and tunable oxygen sensing efficiency.
نویسندگان
چکیده
Doping very small amounts of Ru(II) into a flexible, ultramicroporous, fluorescent Zn(II) coordination polymer produced phosphorescent materials with very high and tunable oxygen quenching efficiency; and a simple color-changing ratiometric oxygen sensor has been constructed.
منابع مشابه
Ultramicroporous metal-organic framework based on 9,10-anthracenedicarboxylate for selective gas adsorption.
An ultramicroporous metal-organic framework based on 9,10-anthracenedicarboxylate (PCN-13) has been synthesized and structurally characterized. The desolvated PCN-13 demonstrates selective adsorption of oxygen and hydrogen over nitrogen and carbon monoxide.
متن کاملOrganic Light Emitting Diodes: Devices and applications
Opto-electronic devices using organic materials are becoming widely desirable for manifold reasons [1-4]. In fact, organic devices have the potential for cost advantages over inorganic devices. In addition, inherent properties of organic materials, such as their flexibility make them well suited for particular applications such as fabrication on a flexible substrate. The materials used in organ...
متن کاملMultifunctional lanthanum tetraphosphonates: flexible, ultramicroporous and proton-conducting hybrid frameworks.
A new flexible ultramicroporous solid, La(H(5)DTMP)·7H(2)O (1), has been crystallized at room temperature using the tetraphosphonic acid H(8)DTMP, hexamethylenediamine-N,N,N',N'-tetrakis(methylenephosphonic acid). Its crystal structure, solved by synchrotron powder X-ray diffraction, is characterised by a 3D pillared open-framework containing 1D channels filled with water. Upon dehydration, a n...
متن کاملDesign of a High Range, High Efficiency Spread Spectrum Transmitter for Audio Communication Applications
This work proposes a direct sequence spread spectrum transmitter with high transmission range and efficiency for audio signals. It is shown that by choosing high process gain for spread spectrum signal the data could reach a range of 55km in the 2.4GHz ISM band. By employing a light modulation scheme, we have a relaxed SNR requirement for having a low bit error rate (BER) which translates to re...
متن کاملHeteronuclear Ir(III)-Ln(III) Luminescent Complexes: Small-Molecule Probes for Dual Modal Imaging and Oxygen Sensing.
Luminescent, mixed metal d-f complexes have the potential to be used for dual (magnetic resonance imaging (MRI) and luminescence) in vivo imaging. Here, we present dinuclear and trinuclear d-f complexes, comprising a rigid framework linking a luminescent Ir center to one (Ir·Ln) or two (Ir·Ln2) lanthanide metal centers (where Ln = Eu(III) and Gd(III), respectively). A range of physical, spectro...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 49 61 شماره
صفحات -
تاریخ انتشار 2013